Evaluating workplace protection factors (WPFs) of different firefighter PPE interface control measures for select volatile organic compounds (VOCs).

Structural firefighters are exposed to a complex set of contaminants and combustion byproducts, including volatile organic compounds (VOCs). Additionally, recent studies have found structural firefighters' skin may be exposed to multiple chemical compounds via permeation or penetration of chemical byproducts through or around personal protective equipment (PPE). This mannequin-based study evaluated the effectiveness of four different PPE conditions with varying contamination control measures (incorporating PPE interface design features and particulate blocking materials) to protect against ingress of several VOCs in a smoke exposure chamber. We also investigated the effectiveness of long-sleeve base layer clothing to provide additional protection against skin contamination. Outside gear air concentrations were measured from within the smoke exposure chamber at the breathing zone, abdomen, and thigh heights. Personal air concentrations were collected from mannequins under PPE at the same general heights and under the base layer at abdomen and thigh heights. Sampled contaminants included benzene, toluene, styrene, and naphthalene. Results suggest that VOCs can readily penetrate the ensembles. Workplace protection factors (WPFs) were near one for benzene and toluene and increased with increasing molecular weight of the contaminants. WPFs were generally lower under hoods and jackets compared to under pants. For all PPE conditions, the pants appeared to provide the greatest overall protection against ingress of VOCs, but this may be due in part to the lower air concentrations toward the floor (and cuffs of pants) relative to the thigh-height outside gear concentrations used in calculating the WPFs. Providing added interface control measures and adding particulate-blocking materials appeared to provide a protective benefit against less-volatile chemicals, like naphthalene and styrene.

Oral nanoparticulate drug delivery systems for the treatment of intestinal bowel disease and colorectal cancer.

INTRODUCTION: The most popular method for delivering drugs locally and systemically is oral. However, the gastrointestinal tract's severe physiological (mucosal and enzymatic barrier) and physicochemical (pH) environment places restrictions on the oral drug delivery system's bioavailability and targeted design. AREAS COVERED: Various nanoparticulate drug delivery systems (NPDDSs) based on lipids or polymers, such as liposomes, solid lipid nanoparticles, polymeric micelles, nanospheres, and nanocapsules and their application in successful treatment of serious diseases such as intestinal bowel disease and colorectal cancer (CRC). These systems can ensure advantages over conventional systems liked improved bioavailability, prolonged residence time, and enhanced solubility of poorly soluble drugs. Moreover, the nature of these NPDDSs led to numerous breakthroughs in bioavailability, active and passive targeting, controlled release, and cost-efficient production on an industrial scale in recent years. EXPERT OPINION: An expert opinion on orally administrable lipid and polymer based NPDDS, the physiological barriers and their use in the treatment of intestinal bowel disease and CRC is provided within this review.

Characterization of inhalation exposures at a wildfire incident during the Wildland Firefighter Exposure and Health Effects (WFFEHE) Study.

Wildland firefighters (WFFs) are exposed to many inhalation hazards working in the wildland fire environment. To assess occupational exposures and acute and subacute health effects among WFFs, the wildland firefighter exposure and health effects study collected data for a 2-year repeated measures study. This manuscript describes the exposure assessment from one Interagency Hotshot Crew (N = 19) conducted at a wildfire incident. Exposures to benzene, toluene, ethylbenzene, xylene isomers, formaldehyde, acetaldehyde, and naphthalene were measured through personal air sampling each work shift. Biological monitoring was done for creatinine-adjusted levoglucosan in urine pre- and post-shift. For 3 days sampling at the wildfire incident, benzene, toluene, ethylbenzene, xylene isomers (m and p, and o) exposure was highest on day 1 (geometric mean [GM] = 0.015, 0.042, 0.10, 0.42, and 0.15 ppm, respectively) when WFFs were not exposed to smoke but used chainsaws to remove vegetation and prepare fire suppression breaks. Exposure to formaldehyde and acetaldehyde was highest on day 2 (GM = 0.03 and 0.036 ppm, respectively) when the WFFs conducted a firing operation and were directly exposed to wildfire smoke. The greatest difference of pre- and post-shift levoglucosan concentrations were observed on day 3 (pre-shift: 9.7 and post-shift: 47 µg/mg creatinine) after WFFs conducted mop up (returned to partially burned area to extinguish any smoldering vegetation). Overall, 65% of paired samples (across all sample days) showed a post-shift increase in urinary levoglucosan and 5 firefighters were exposed to benzene at concentrations at or above the National Institute for Occupational Safety and Health (NIOSH) recommended exposure limit. Our findings further demonstrate that exposure to inhalation hazards is one of many risks that wildland firefighters experience while suppressing wildfires.

Modified Taylor Impact Tests with Profiled Copper Cylinders: Experiment and Optimization of Dislocation Plasticity Model.

Current progress in numerical simulations and machine learning allows one to apply complex loading conditions for the identification of parameters in plasticity models. This possibility expands the spectrum of examined deformed states and makes the identified model more consistent with engineering practice. A combined experimental-numerical approach to identify the model parameters and study the dynamic plasticity of metals is developed and applied to the case of cold-rolled OFHC copper. In the experimental part, profiled projectiles (reduced cylinders or cones in the head part) are proposed for the Taylor impact problem for the first time for material characterization. These projectiles allow us to reach large plastic deformations with true strains up to 1.3 at strain rates up to 105 s-1 at impact velocities below 130 m/s. The experimental results are used for the optimization of parameters of the dislocation plasticity model implemented in 3D with the numerical scheme of smoothed particle hydrodynamics (SPH). A Bayesian statistical method in combination with a trained artificial neural network as an SPH emulator is applied to optimize the parameters of the dislocation plasticity model. It is shown that classical Taylor cylinders are not enough for a univocal selection of the model parameters, while the profiled cylinders provide better optimization even if used separately. The combination of different shapes and an increase in the number of experiments increase the quality of optimization. The optimized numerical model is successfully validated by the experimental data about the shock wave profiles in flyer plate experiments from the literature. In total, a cheap, simple, but efficient route for optimizing a dynamic plasticity model is proposed. The dislocation plasticity model is extended to estimate grain refinement and volume fractions of weakened areas in comparison with experimental observations.

Evaluating Exposure to VOCs and Naphthalene for Firefighters Wearing Different PPE Configurations through Measures in Air, Exhaled Breath, and Urine.

Firefighters are at an increased risk of cancer due to their occupational exposure to combustion byproducts, especially when those compounds penetrate the firefighter personal protective equipment (PPE) ensemble. This has led to questions about the impact of base layers (i.e., shorts vs. pants) under PPE ensembles. This study asked 23 firefighters to perform firefighting activities while wearing one of three different PPE ensembles with varying degrees of protection. Additionally, half of the firefighters unzipped their jackets after the scenario while the other half kept their jackets zipped for five additional minutes. Several volatile organic compound (VOC) and naphthalene air concentrations outside and inside of hoods, turnout jackets, and turnout pants were evaluated; biological (urinary and exhaled breath) samples were also collected. VOCs and naphthalene penetrated the three sampling areas (hoods, jackets, pants). Significant (p-value < 0.05) increases from pre- to post-fire for some metabolites of VOCs (e.g., benzene, toluene) and naphthalene were found. Firefighters wearing shorts and short sleeves absorbed higher amounts of certain compounds (p-value < 0.05), and the PPE designed with enhanced interface control features appeared to provide more protection from some compounds. These results suggest that firefighters can dermally absorb VOCs and naphthalene that penetrate the PPE ensemble.

Effect of Copper Segregation at Low-Angle Grain Boundaries on the Mechanisms of Plastic Relaxation in Nanocrystalline Aluminum: An Atomistic Study.

The paper studies the mechanisms of plastic relaxation and mechanical response depending on the concentration of Cu atoms at grain boundaries (GBs) in nanocrystalline aluminum with molecular dynamics simulations. A nonmonotonic dependence of the critical resolved shear stress on the Cu content at GBs is shown. This nonmonotonic dependence is related to the change in plastic relaxation mechanisms at GBs. At a low Cu content, GBs slip as dislocation walls, whereas an increase in Cu content involves a dislocation emission from GBs and grain rotation with GB sliding.

Use of Preliminary Exposure Reduction Practices or Laundering to Mitigate Polycyclic Aromatic Hydrocarbon Contamination on Firefighter Personal Protective Equipment Ensembles.

Chronic health risks associated with firefighting continue to be documented and studied, however, the complexity of occupational exposures and the relationship between occupational exposure and contaminated personal protective equipment (PPE) remains unknown. Recent work has revealed that common PPE cleaning practices, which are becoming increasingly more common in the fire service, are not effective in removing certain contaminants, such as polycyclic aromatic hydrocarbons (PAHs), from PPE. To better understand the relationship between contaminated firefighter PPE and potential exposure to PAHs, and to gain further understanding of the efficacy of cleaning practices, we used a standardized fire exposure simulator that created repeatable conditions and measured PPE surface contamination levels via wipe sampling and filters attached to firefighter gear worn by standing mannequins. This study examined the effects of repeated (40 cycles) PPE cleaning (laundering and on-scene preliminary exposure reduction (PER) techniques) and repeated exposures on PAH concentration on different surfaces. Further exploration included examination of contamination breakthrough of turnout jackets (comparing outer shell and interior liner) and evaluation of off-gassing PAHs from used gear after different cleaning treatments. When compared by jacket closure type (zipper and hook and dee), total PAH concentration wiped from gear after exposure and cleanings showed no significant differences. Regression analysis indicated that there was no effect of repeated exposures on PAH contamination levels (all sampling sites combined; before fire 10, 20, and 40; after fire 1, 10, 20, and 40; p-value > 0.05). Both laundering and on-scene PER significantly reduced contamination levels on the exterior pants and helmets and were effective at reducing PAH contamination. The jacket outer shell had significantly higher PAH contamination than the jacket liner. Both laundering and wet soap PER methods (post-fire) are effective in reducing surface contamination and appear to prevent accumulation of contamination after repeated exposures. Semi-volatile PAHs deep within the fibers of bulky PPE are not effectively reduced via PER or machine laundering, therefore, permitting continued off-gassing of these compounds. Further research is needed to identify the most effective laundering methods for firefighter turnout gear that considers the broad spectrum of common contaminants.

Evaluation and Improvement of the Stability of Poly(ethylene oxide)-based Solid-state Batteries with High-Voltage Cathodes.

Solid-state batteries (SSBs) with high-voltage cathode active materials (CAMs) such as LiNi1-x-y Cox Mny O2 (NCM) and poly(ethylene oxide) (PEO) suffer from "noisy voltage" related cell failure. Moreover, reports on their long-term cycling performance with high-voltage CAMs are not consistent. In this work, we verified that the penetration of lithium dendrites through the solid polymer electrolyte (SPE) indeed causes such "noisy voltage cell failure". This problem can be overcome by a simple modification of the SPE using higher molecular weight PEO, resulting in an improved cycling stability compared to lower molecular weight PEO. Furthermore, X-ray photoelectron spectroscopy analysis confirms the formation of oxidative degradation products after cycling with NCM, for what Fourier transform infrared spectroscopy is not suitable as an analytical technique due to its limited surface sensitivity. Overall, our results help to critically evaluate and improve the stability of PEO-based SSBs.

Novel sulfur-doped single-ion conducting multi-block copolymer electrolyte.

Solid-state lithium batteries are considered one of the most promising candidates for future electrochemical energy storage. However, both inorganic solid electrolytes (such as oxide-based or sulfide-based materials) and polymer electrolytes still have to overcome several challenges to replace the currently used liquid organic electrolytes. An increasingly adopted approach to overcome these challenges relies on the combination of different electrolyte systems. Herein, we report the synthesis and characterization of a novel sulfur-doped single-ion conducting multi-block copolymer (SIC-BCE) system. This SIC-BCE may serve as interlayer between the electrodes and the sulfidic electrolyte such as Li6PS5Cl, thus benefitting of the high ionic conductivity of the latter and the favorable interfacial contact and electrochemical stability of the polymer. The polymer shows excellent ionic conductivity when swollen with ethylene carbonate and allows for stable stripping/plating of lithium, accompanied by a suitable electrochemical stability towards reduction and oxidation. First tests in symmetric Cu|SIC-BCE|Li6PS5Cl|SIC-BCE|Cu cells confirm the general suitability of the polymer to stabilize the electrode|electrolyte interface by preventing the direct contact of the sulfidic electrolyte with, e.g., metallic copper foils.

Influence of Polymer Backbone Fluorination on the Electrochemical Behavior of Single-Ion Conducting Multiblock Copolymer Electrolytes.

The presence of fluorine, especially in the electrolyte, frequently has a beneficial effect on the performance of lithium batteries owing to, for instance, the stabilization of the interfaces and interphases with the positive and negative electrodes. However, the presence of fluorine is also associated with reduced recyclability and low biodegradability. Herein, we present a single-ion conducting multiblock copolymer electrolyte comprising a fluorine-free backbone and compare it with the fluorinated analogue reported earlier. Following a comprehensive physicochemical and electrochemical characterization of the copolymer with the fluorine-free backbone, the focus of the comparison with the fluorinated analogue was particularly on the electrochemical stability toward oxidation and reduction as well as the reactions occurring at the interface with the lithium-metal electrode. To deconvolute the impact of the fluorine in the ionic side chain and the copolymer backbone, suitable model compounds were identified and studied experimentally and theoretically. The results show that the absence of fluorine in the backbone has little impact on the basic electrochemical properties, such as the ionic conductivity, but severely affects the electrochemical stability and interfacial stability. The results highlight the need for a very careful design of the whole polymer for each desired application, essentially, just like for liquid electrolytes.

Firefighters' urinary concentrations of VOC metabolites after controlled-residential and training fire responses.

INTRODUCTION: Firefighters are exposed to volatile organic compounds (VOCs) during structural fire responses and training fires, several of which (e.g., benzene, acrolein, styrene) are known or probable carcinogens. Exposure studies have found that firefighters can absorb chemicals like benzene even when self-contained breathing apparatus (SCBA) are worn, suggesting that dermal absorption contributes to potentially harmful exposures. However, few studies have characterized VOC metabolites in urine from firefighters. OBJECTIVES: We quantified VOC metabolites in firefighters' urine following live firefighting activity across two field studies. METHODS: In two separate controlled field studies, spot urine was collected before and 3 h after firefighters and firefighter students responded to simulated residential and training fires. Urine was also collected from instructors from the training fire study before the first and 3 h after the last training scenario for each day (instructors led three training scenarios per day). Samples were analyzed for metabolites of VOCs to which firefighters may be exposed. RESULTS: In the residential fire study, urinary metabolites of xylenes (2MHA), toluene (BzMA), and styrene (MADA) increased significantly (at 0.05 level) from pre- to post-fire. In the training fire study, MADA concentrations increased significantly from pre- to post-fire for both firefighter students and instructors. Urinary concentrations of benzene metabolites (MUCA and PhMA) increased significantly from pre- to post-fire for instructors, while metabolites of xylenes (3MHA+4MHA) and acrolein (3HPMA) increased significantly for firefighter students. The two highest MUCA concentrations measured post-shift from instructors exceeded the BEI of 500 µg/g creatinine. CONCLUSIONS: Some of the metabolites that were significantly elevated post-fire are known or probable human carcinogens (benzene, styrene, acrolein); thus, exposure to these compounds should be eliminated or reduced as much as possible through the hierarchy of controls. Given stringent use of SCBA, it appears that dermal exposure contributes in part to the levels measured here.

Characterizing exposure to benzene, toluene, and naphthalene in firefighters wearing different types of new or laundered PPE.

The fire service has become more aware of the potential for adverse health outcomes due to occupational exposure to hazardous combustion byproducts. Because of these concerns, personal protective equipment (PPE) manufacturers have developed new protection concepts like particulate-blocking hoods to reduce firefighters' exposures. Additionally, fire departments have implemented exposure reduction interventions like routine laundering of PPE after fire responses. This study utilized a fireground exposure simulator (FES) with 24 firefighters performing firefighting activities on three consecutive days wearing one of three PPE ensembles (stratified by hood design and treatment of PPE): 1) new knit hood, new turnout jacket and new turnout pants 2) new particulate-blocking hood, new turnout jacket and new turnout pants or 3) laundered particulate-blocking hood, laundered turnout jacket and laundered turnout pants. As firefighters performed the firefighting activities, personal air sampling on the outside and inside the turnout jacket was conducted to quantify exposures to volatile organic compounds (VOCs) and naphthalene. Pre- and immediately post-fire exhaled breath samples were collected to characterize the absorption of VOCs. Benzene, toluene, and naphthalene were found to diffuse through and/or around the turnout jacket, as inside jacket benzene concentrations were often near levels reported outside the turnout jacket (9.7-11.7% median benzene reduction from outside the jacket to inside the jacket). The PPE ensemble did not appear to affect the level of contamination found inside the jacket for the compounds evaluated here. Benzene concentrations in exhaled breath increased significantly from pre to post-fire for all three groups (p-values < 0.05). The difference of pre-to post-fire benzene exhaled breath concentrations were positively associated with inside jacket and outside jacket benzene concentrations, even though self-contained breathing apparatus (SCBA) were worn during each response. This suggests the firefighters can absorb these compounds via the dermal route.

Airborne contamination during post-fire investigations: Hot, warm and cold scenes.

Fire investigators may be occupationally exposed to many of the same compounds as the more widely studied fire suppression members of the fire service but are often tasked with working in a given exposure for longer periods ranging from hours to multiple days and may do so with limited personal protective equipment. In this study, we characterize the area air concentrations of contaminants during post-fire investigation of controlled residential fires with furnishings common to current bedroom, kitchen and living room fires in the United States. Area air sampling was conducted during different investigation phases including when investigations might be conducted immediately after fire suppression and extended out to 5 days after the fire. Airborne particulate over a wide range of dimensions, including sub-micron particles, were elevated to potentially unhealthy levels (based on air quality index) when averaged over a 60 min investigation period shortly after fire suppression with median PM2.5 levels over 100 µg/m3 (range 16-498 µg/m3) and median peak transient concentrations of 1,090 µg/m3 (range 200-23,700 µg/m3) during drywall removal or shoveling activities. Additionally, airborne aldehyde concentrations were elevated compared to volatile organic compounds with peak values of formaldehyde exceeding NIOSH ceiling limits during the earliest investigation periods (median 356 µg/m3, range: 140-775 µg/m3) and occasionally 1 day post-fire when the structure was boarded up before subsequent investigation activities. These results highlight the need to protect investigators' airways from particulates when fire investigation activities are conducted as well as during post-fire reconstruction activities. Additionally, vapor protection from formaldehyde should be strongly considered at least through investigations occurring 3 days after the fire and personal formaldehyde air monitoring is recommended during investigations.

Block copolymers as (single-ion conducting) lithium battery electrolytes.

Solid-state batteries are considered the next big step towards the realization of intrinsically safer high-energy lithium batteries for the steadily increasing implementation of this technology in electronic devices and particularly, electric vehicles. However, so far only electrolytes based on poly(ethylene oxide) have been successfully commercialized despite their limited stability towards oxidation and low ionic conductivity at room temperature. Block copolymer (BCP) electrolytes are believed to provide significant advantages thanks to their tailorable properties. Thus, research activities in this field have been continuously expanding in recent years with great progress to enhance their performance and deepen the understanding towards the interplay between their chemistry, structure, electrochemical properties, and charge transport mechanism. Herein, we review this progress with a specific focus on the block-copolymer nanostructure and ionic conductivity, the latest works, as well as the early studies that are fr"equently overlooked by researchers newly entering this field. Moreover, we discuss the impact of adding a lithium salt in comparison to single-ion conducting BCP electrolytes along with the encouraging features of these materials and the remaining challenges that are yet to be solved.

A phosphoproteomic approach reveals that PKD3 controls PKA-mediated glucose and tyrosine metabolism.

Members of the protein kinase D (PKD) family (PKD1, 2, and 3) integrate hormonal and nutritional inputs to regulate complex cellular metabolism. Despite the fact that a number of functions have been annotated to particular PKDs, their molecular targets are relatively poorly explored. PKD3 promotes insulin sensitivity and suppresses lipogenesis in the liver of animals fed a high-fat diet. However, its substrates are largely unknown. Here we applied proteomic approaches to determine PKD3 targets. We identified more than 300 putative targets of PKD3. Furthermore, biochemical analysis revealed that PKD3 regulates cAMP-dependent PKA activity, a master regulator of the hepatic response to glucagon and fasting. PKA regulates glucose, lipid, and amino acid metabolism in the liver, by targeting key enzymes in the respective processes. Among them the PKA targets phenylalanine hydroxylase (PAH) catalyzes the conversion of phenylalanine to tyrosine. Consistently, we showed that PKD3 is activated by glucagon and promotes glucose and tyrosine levels in hepatocytes. Therefore, our data indicate that PKD3 might play a role in the hepatic response to glucagon.

Characterizing exposures to flame retardants, dioxins, and furans among firefighters responding to controlled residential fires.

Firefighters may encounter items containing flame retardants (FRs), including organophosphate flame retardants (OPFRs) and polybrominated diphenyl ethers (PBDEs), during structure fires. This study utilized biological monitoring to characterize FR exposures in 36 firefighters assigned to interior, exterior, and overhaul job assignments, before and after responding to controlled residential fire scenarios. Firefighters provided four urine samples (pre-fire and 3-h, 6-h, and 12-h post-fire) and two serum samples (pre-fire and approximately 23-h post-fire). Urine samples were analyzed for OPFR metabolites, while serum samples were analyzed for PBDEs, brominated and chlorinated furans, and chlorinated dioxins. Urinary concentrations of diphenyl phosphate (DPhP), a metabolite of triphenyl phosphate (TPhP), bis(1,3-dichloro-2-propyl) phosphate (BDCPP), a metabolite of tris(1,3-dichloro-2-propyl) phosphate (TDCPP), and bis(2-chloroethyl) phosphate (BCEtP), a metabolite of tris(2-chloroethyl) phosphate (TCEP), increased from pre-fire to 3-hr and 6-hr post-fire collection, but only the DPhP increase was statistically significant at a 0.05 level. The 3-hr and 6-hr post-fire concentrations of DPhP and BDCPP, as well as the pre-fire concentration of BDCPP, were statistically significantly higher than general population levels. BDCPP pre-fire concentrations were statistically significantly higher in firefighters who previously participated in a scenario (within the past 12 days) than those who were responding to their first scenario as part of the study. Similarly, firefighters previously assigned to interior job assignments had higher pre-fire concentrations of BDCPP than those previously assigned to exterior job assignments. Pre-fire serum concentrations of 2,3,4,7,8-pentachlorodibenzofuran (23478-PeCDF), a known human carcinogen, were also statistically significantly above the general population levels. Of the PBDEs quantified, only decabromodiphenyl ether (BDE-209) pre- and post-fire serum concentrations were statistically significantly higher than the general population. These results suggest firefighters absorbed certain FRs while responding to fire scenarios.

Brass instruments as a cascade of two-port networks: Transfer functions, chain parameters, and power efficiency in theory and practice.

This paper investigates how two-port network theory as a means for system identification can be applied to the analysis of brass instruments. A special focus is placed on the energy conversion efficiency as this is limited by inner damping, which receives much attention by expert players and makers of brasses. Theory suggests that a reconstruction of the 2 × 2 matrix representing the network requires input impedance and transfer function for two different boundary conditions. Besides the normal case of free sound radiation, instruments are also analyzed with the bell closed by a spherical cap. For this purpose, a customized 3D-printed spherical cap was fabricated and attached to the bell. Four measured spectra and the passivity condition over-determine the set of system equations. It is shown how to take advantage of this freedom when analyzing wind instruments. Measurements and simulations of a trumpet and a trombone are presented and compared.

Protein Kinase D2 drives chylomicron-mediated lipid transport in the intestine and promotes obesity.

Lipids are the most energy-dense components of the diet, and their overconsumption promotes obesity and diabetes. Dietary fat content has been linked to the lipid processing activity by the intestine and its overall capacity to absorb triglycerides (TG). However, the signaling cascades driving intestinal lipid absorption in response to elevated dietary fat are largely unknown. Here, we describe an unexpected role of the protein kinase D2 (PKD2) in lipid homeostasis. We demonstrate that PKD2 activity promotes chylomicron-mediated TG transfer in enterocytes. PKD2 increases chylomicron size to enhance the TG secretion on the basolateral side of the mouse and human enterocytes, which is associated with decreased abundance of APOA4. PKD2 activation in intestine also correlates positively with circulating TG in obese human patients. Importantly, deletion, inactivation, or inhibition of PKD2 ameliorates high-fat diet-induced obesity and diabetes and improves gut microbiota profile in mice. Taken together, our findings suggest that PKD2 represents a key signaling node promoting dietary fat absorption and may serve as an attractive target for the treatment of obesity.

Motion of Particles in a Monolayer Induced by Coalescing of a Bubble with a Planar Air-Water Interface.

The motion of particles in a monolayer induced by the coalescing of a bare bubble with a planar air-water interface was investigated in a modified Langmuir trough. Experiments were performed to understand the effect of particle hydrophobicity, subphase pH, packing density, the presence of a weak surfactant, and particle size distribution on the behavior of particle movement in the monolayer during the coalescence process. Video tracking software was used to track the particles and extract data based on the video footage. Visual inspection indicated that the coalescence of the bubble with the monolayer was a chaotic process which led the interface to oscillate to an extent that the particles underwent complete rearrangement. A simple analysis was carried out on the main forces involved in particle motion and rearrangement at the oscillating air-water interface. The motion characteristic of particles was evaluated by speed and mean-square displacement (MSD). The results showed that the butanol-treated particles had higher speed and MSD than the particles with a stronger affinity to the air-water interface. Similar results were also found at high subphase pH and low packing factor.